Service de Physique de l'Etat Condensé

 


Celine Fiorini

Celine FIORINI

Service de Physique et Chimie des Surfaces et des Interfaces (SPCSI)
Laboratoire d'Electronique et nanoPhotonique Organique (LEPO)

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Fonction

Chercheur

Sujets de recherche

- Optique non-linéaire de nano-objets
- Etude STM de l’auto-assemblage bidimensionnel de molécules organiques,

- Optique et optique nonlinéaire en milieu organique
(fluorescence, absorption multiphotonique, conversion de fréquence …)
- Microstructuration de polymères par voie optique
- Etude de l’organisation de la matière à différentes échelles par des techniques conjointes de spectroscopie et de microscopie à sonde locale (STM, AFM)
- Applications : marquage de l’ADN, optimisation de composants optoélectroniques (cellules solaires plastiques, diodes organiques électroluminescentes, capteurs chimiques).

CV

2004-       Direction des Sciences de la Matière / DRECAM/SPCSI
1995-2004 Chercheur CEA, Direction de la Recherche Technologique / Laboratoire Composants Organiques

1992–1995 : CEA Saclay (DTA/DEIN), Thèse en Sciences Physiques, optique et photonique (Paris XI-Orsay),
Etude des non-linéarités du second ordre induites par voie optique, application à l'orientation optique de molécules organiques.

1989 - 1992 : Ecole Supérieure d'Optique, Orsay

Publications scientifiques

57 publications dans des revues à comité de lecture, Hirsh factor=19

50 dernières publications (publiCEA) 

- I. Berline, C. Fiorini-Debuisschert, C. Royal, L. Douillard, F. Charra, Molecular second harmonic generation induced at a metallic tip, J. of Appl. Phys., 104, 103113 (2008).

- E. Ishow, A. Brosseau, G. Clavier, K. Nakatani, P. Tauc, C. Fiorini-Debuisschert, S. Neveau, O. Sandre, A. Leaustic, Multicolor emission of small molecule-based amorphous thin films and nanoparticles with a single excitation wavelength, Chem Mat., 20(21), 6597, (2008).

- D. Bleger, D. Kreher, F. Mathevet, AJ Attias, I. Arfaoui, G. Metgé, L. Douillard, C. Fiorini-Debuisschert, F. Charra, Periodic positioning of multilayered [2.2]Paracyclophane based nanopillars, Angew Chem Int Ed., 47(44), 8412 (2008).

- G. Schull, H. Ness, L. Douillard, C. Fiorini-Debuisschert, F. Charra, F. Mathevet, D. Kreher, AJ Attias, Single atom substitution for marking and motion tracking of individual molecules by scanning tunneling microscopy, J. Phys Chem C, 112(36), 14058 (2008).

- G Bordeau, R Lartia, G Metge, C Fiorini-Debuisschert,  F Charra, and M-P Teulade-Fichou,   Trinaphthylamines as robust organic materials for two-photon-induced fluorescence, J Am Chem Soc, 130(50), 16836 (2008).

- R. Lartia, C. Allain, G. Bordeau, F. Schmidt, C. Fiorini-Debuisschert, F. Charra, MP Teulade-Fichou, « Synthetic strategies to derivatizable Triphenylamines displaying high two-photon absortion", J. Org. Chem., 73(5), 1732, (2008).

Bleger, D. Kreher, F. Mathevet, AJ Attias, G. Schull, A. Huard, L Douillard, C. Fiorini-Debuisschert, F. Charra, A SURFACE-ACTIVATED NON-COVALENT BONDING FOR RATIONAL DESIGN OF HIERARCHICAL MOLECULAR SELF-ASSEMBLIES, Angewandte Chem. Int. Ed., 46, 7404, (2007).

- C. Hubert , Fiorini-Debuisschert , L Rocha, et al., SPONTANEOUS PHOTOINDUCED PATTERNING OF AZO-DYE POLYMER FILMS : THE FACTS, J Opt Soc Am. B, 24(8): 1839-1846 (2007).

- L. Douillard, F. Charra, C. Fiorini et al., OPTICAL PROPERTIES OF METAL NANOPARTICLES AS PROBED BY PHOTOEMISSION ELECTRON MICROSCOPY, J. Appl. Phys., 101(8) 083518  (2007).

- C. Allain, F. Schmidt, R. Lartia, G. Bordeau, C. Fiorini-Debuisschert, F. Charra, P. Tauc, MP Teulade-Fichou, « VINYL-PYRIDINIUM TRIPHENYLAMINES: NOVEL FAR-RED EMITTERS WITH HIGH PHOTOSTABILITY AND TWO-PHOTON ABSORPTION PROPERTIES FOR STAINING DNA”, ChemBioChem 8(4), 424-433 (2007).

- G. Schull , L. Douillard, C. Fiorini-Debuisschert, et al., SELECTIVITY OF SINGLE MOLECULE DYNAMICS IN 2D MOLECULAR SIEVES, Adv. Materials, 18(22), 2954 (2006).

- G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, SINGLE MOLECULE DYNAMICS IN A SELF-ASSEMBLED 2D MOLECULAR SIEVE, Nanolett., 6(7) 1360 (2006).

- C. Cocoyer, L Rocha, L Sicot, C. Fiorini-Debuisschert et al., IMPLEMENTATION OF SUBMICROMETRIC PERIODIC SURFACE STRUCTURES : TOXARDS IMPROVEMENT OF ORGANIC SOLAR CELL PERFORMANCES, Appl. Phys Lett, 88(13), 133108 (2006).

- JT Zoueu, C. Fiorini-Debuisschert, F. Charra et al., TRANSIENT SECOND HARMONIC GENERATION IN A CYANINE LIQUID DYE SOLUTION, Chem Phys Lett., 419(4-6), 454, (2006).

- C. Hubert, C. Fiorini-Debuisschert, I Hassiaoui et al., EMISSION PROPERTIES OF AN ORGANIC  LIGHT EMITTING DIODE PATTERNED BY A PHOTOINDUCED AUTOSTRUCTURATION PROCESS, Appl. Phys Lett, 87(19), 191105 (2005).

- C. Hubert, C. Fiorini-Debuisschert, P. Raimond, JM Nunzi, JJ Simon, L. Escoubas, SPONTANEOUS PHOTOINDUCED STRCUTURATION OF THE SURFACE OF AZOBENZENE POLYMER FILMS BY THE MOLECULAR MIGRATION EFFECT, Nonlinear Opt., Quant. Opt., Optics concepts in modern opt., 31(1-4), 221, (2004).

- M. Marcaccio, J.A. McCleverty, W. Akemann, C.Fiorini, et al., PHOTOINDUCED CHARGE SEPARATION IN MOLYBDENUM-MONOSTRYRIL-FERROCENYL-STILBENE, J. Photochem. Photobiol. A 163(3), 413 (2004).

- C. Hubert, C. Fiorini-Debuisschert, I Maurin et al., SPONTANEOUS PATTERNING OF HEXAGONAL STRCUTURES IN AN AZO-POLYMER USING LIGHT-CONTROLLED MASS TRANSPORT, Adv. Mater., 14(10), 729 (2002).

- N. Sertova, I. Petkov, C. Fiorini et al., PHOTOINDUCED SURFACE RELIEF GRATING FORMATION IN POLYMERS DOPED WITH BIS-AZODYES,  Mol. Cryst. Liq Cryst, 374, 77 (2002).

- L. Rocha, V. Dumarcher, C. Denis, C. Fiorini et al., LASER EMISSION IN PERIODICALLY MODULATED POLYMER FILMS, J. Appl Phys, 89(5), 3067, (2001).

- V. Dumarcher, L. Rocha, C. Denis, C. Fiorini et al., POLYMER THIN FILM DISTRIBUTED FEEDBACK TUNABLE LASERS,  J. Opt A- Pure Appl Opt, 4, 279 (2000).

- L. Sicot, C. Fiorini, A. Lorin et al., IMPROVEMENT OF THE PHOTOVOLTAIC PROPERTIES OF POLYTHIOPHENE BASED CELLS, Sol Energ Mat Sol C, 63 (1), 49 (2000).

- K.P. Kretsch, W.J. Blau, V. Dumarcher, C. Fiorini et al., DISTRIBUTED FEEDBACK LASER ACTION FROM POLYMERIC WAVEGUIDES DOPED WITH OLIGO PHENYLENE VINYLENE MODEL COMPOUNDS, Appl. Phys Lett, 76(16), 2149 (2000).

- B. Paci, C. Schmidt, C. Fiorini, et al.,  NONLINEAR OPTICAL PROPERTIES OF PUSH-PULL STILBENE BASED ON A STRONG CARBOCATION ACCEPTOR MOIETY,  J. Chem Phys, 111(16), 7486 (1999).

- C. Arbez-Gindre, CG Screttas, C. Fiorni et al., ORGANOLITHIUM REAGENTS BEARING NONLINEAR OPTICAL CHROMOPHORES. SYNTHEIS OF TRIARYLMETHANE DYES, Tetrahedron Lett 40(41), 7413 (1999).

- H. Bock, RC Advincula, EF Aust , C. Fiorini et al., SUPRAMOLECULAR ASSEMBLIES FOR SECOND ORDER NONLINEAR OPTICS STABILIZED BY ELECTROSTATIC INTERACTIONS, J Nonlinear Opt Phys, 7(3), 385, (1998).

- C. Sentein, C. Fiorini, A Lorin et al., MOLECULAR RECTIFICATION IN ORIENTED POLYMERS, J. Chem Phys PCB 95 (6), 1331, (1998).

- C. Fiorini, JM Nunzi, DYNAMICS AND EFFICIENCY OF ALL-OPTICAL POLING IN POLYMERS, Chem Phys Lett, 286(5-6), 415, (1998).

- J.M. Nunzi, C. Fiorini, AC Etilé, et al., ALL-OPTICAL POLING IN POLYMERS : DYNAMICAL ASPECTS AND PERSPECTIVES, Pure Appl Opt 7(2), 141, (1998).

- C. Sentein, C. Fiorini, A. Lorin et al., STUDY OF ORIENTATION INDUCED MOLECULAR RECTIFICATION IN POLYMER FILMS,  Opt Mater 9 (1-4), 316, (1998).

- S. Delysse, V Dumarcher, P Filloux, C. Fiorini et al., MULTIPHOTON ABSORPTION IN ORGANIC DYE SOLUTIONS, Opt Mater 9 (1-4), 347, (1998).

- P. Lefin, C. Fiorini, JM Nunzi, ANISOTROPY OF THE PHOTOINDUCED TRANSLATION DIFFUSION OF AZO-BENZENE DYES IN POLYMER MATRICES, Pure Appl Opt, 7(1), 71 (1998).

- C. Sentein, C. Fiorini, A. Lorin et al., MOLECULAR RECTIFICATION IN ORIENTED POLYMER STRUCTURES, Synthetic Met, 91(1-3), 81 (1997).

- C. Fiorini, F. Charra, P. Raimond et al., ALL-OPTICAL INDUCTION OF NONCENTROSYMMETRY IN A TRANSPARENT NONLINEAR POLYMER ROD, Opt lett., 22(24), 1846, (1997).

- A.C. Etilé, C. Fiorini, F. Charra et J.M. Nunzi, PHASE-COHERENT CONTROL OF THE MOLECULAR POLAR ORDER IN POLYMERS USING DUAL-FREQUENCY INTERFERENCES BETWEEN CIRCULARLY POLARIZED BEAMS,  Phys Rev A, 56 (5) 3888, (1997).

- C. Sentein, C. Fiorini, A. Lorin, et J.M. Nunzi, MOLECULAR RECTIFICATION IN ORIENTED POLYMER STRUCTURES,, Adv Mater, 9(10), 809 (1997).

- C.Fiorini, F.Charra, J.M.Nunzi, et P.Raimond, QUASI-PERMANENT ALL-OPTICAL ENCODING OF NON-CENTROSYMMETRY IN AZO-DYE POLYMERS, J Opt Soc Am B 14(8), 1984, (1997).

- C. Fiorini, J.M. Nunzi, F. Charra, F. Kajzar, M. Lequan, R.M. Lequan et K. Chane-Ching, LIGHT-INDUCED ORIENTATION OF A LOW ABSORBING PHOPHINE OXIDE AZO-DYE/PMMA COPOLYMER : TOWARDS A TRADE-OFF BETWEEN TRANSPARENCY AND PHOTOINDUCED NON-LINEARITY, Chem Phys Lett, 271(4-6) 335, (1997).

- I. Lampre, D. Markovitsi, C. Fiorini, F. Charra, M. Veber, OPTICAL PROPERTIES OF TRIARYLPYRYLIUM DIMERS, J Phys Chem – US, 100(25), 10701, (1996).

- W. Chalupczak, C. Fiorini, F.Charra, J.M.Nunzi et P. Raimond , EFFICIENT ALL-OPTICAL POLING OF AN AZO-DYE COPOLYMER USING A LOW POWER LASER, Opt Commun, 126 (1-3), 103 (1996).

- C.Fiorini, F.Charra, J.M.Nunzi, I.D.W. Samuel et J.Zyss, LIGHT-INDUCED SECOND HARMONIC GENERATION IN AN OCTUPOLAR DYE, Opt Lett 20(24), 2469, (1995).

- C.Fiorini, F.Charra and J.M.Nunzi, SIX-WAVE MIXING PROBE OF LIGHT INDUCED SECOND HARMONIC GENERATION : EXAMPLE OF DYE SOLUTIONS, J Opt Soc Am B, 11(12), 2347, (1994).

- C.Fiorini, C.Sauteret, C.Rouyer, N.Blanchot, S.Seznec and A.Migus, TEMPORAL ABERRATIONS DUE TO MISALIGNMENT OF A STRETCHER-COMPRESSOR SYSTEM AND COMPENSATION, IEEE J Quantum Elect 30(7), 1662, (1994).

- D.Markovitsi, H.Sigal, C.Ecoffet, P.Millie, F.Charra, C.Fiorini, J.M.Nunzi, H.Strzelecka, M.Veber, C.Jallabert, CHARGE TRANSFER IN TRYARYL PYRYLIUM CATIONS. THEORETICAL AND EXPERIMENTAL STUDY, Chem Phys, 182(1), 69, (1994).

- J.M.Nunzi, F.Charra, C.Fiorini and J.Zyss, TRANSIENT OPTICALLY-INDUCED NON-CENTROSYMMETRY IN A SOLUTION OF OCTUPOLAR MOLECULES, Chem Phys Lett., 219(5-6), 349, (1994).

Actes de conférences soumis à comité de lecture

- C. Fiorini-Debuisschert, I. Berline, G. Metgé, A. Apetrei, I. Arfaoui, F. Charra, D. Bléger, D. Kreher, F. Mathevet, AJ Attias, Controlling molecular organization for the realization of sub-wavelength light sources, proceedings "5th International Symposium on Materials and Devices for nonlinear Optics", Porquerolles, (26 Juin-1er Juil. 2009). 

- C. Fiorini-Debuisschert, I. Berline, G. Metgé, F. Charra, M. Mihaly, C. Allain, G. Bordeau, MP Teulade-Fichou, Two-phon microscopy : from the optimisation of fluorescent DNA labels to local probe scanning second harmonic generation microscopy, Nonlin. Opt. and Quantum Optics, 38(3-4), 271 (2009).

- A.A. Apostoluk, L. Rocha, C. Fiorini-Debuisschert et al.,  SEMICONDUCTING DYE-FUNCTIONALISED POLED POLYMERS FOR PHOTOVOLTAIC APPLICATIONS, Materials Science Poland, 22(4) 397 (2004).

- C. Hubert, E. Malcor, I. Maurin , C. Fiorini et al., MICROSTRUCTURING OF POLYMERS USING A LIGHT CONTROLLED MOLECULAR MIGRATION PROCESS, Appl. Surf Science, 186 (1-4), 29, (2002).

- L. Rocha, V. Dumarcher, E. Malcor, C. Fiorini et al., PHOTOINDUCED MICROSTRUCTURED POLYMERS FOR THE OPTIMISATION AND CONTROL OF ORGANIC DEVICES EMISSION PROPERTIES, Synthetic Met, 127 (1-3), 75, (2002).

- J.M. Nunzi, C. Fiorini, G. de Veyrac, et al., Mol Cryst Liq Cryst, 353, 427 (2000).

- C. Fiorini, N. Prudhomme, G. de Veyrac, et al., MOLECULAR MIGRATION MECHANISM FOR LASER INDUCED SURFACE RELIEF GRATING FORMATION , Synthetic Met, 115 (1-3), 121, (2000).

- C. Fiorini, J.M. Nunzi, P. Raimond et al. , SYMMETRY OF THE ALL-OPTICAL ORIENTATION DYNAMICS OF AN OCTUPOLAR AZO-DYE SALT,  Synthetic Met, 115 (1-3), 127, (2000).

- C. Fiorini, S. Delysse, J.M. Nunzi, et al., PHOTOPHYSICS OF THE ALL-OPTICAL ORIENTATION DYNAMICS OF A PYRYLIUM SALT,  Synthetic Met, 115 (1-3), 133, (2000).

- C. Sentein, C. Fiorini, A. Lorin, POLING INDUCED IMPROVEMENT OF ORGANIC POLYMER DEVICE EFFICIENCY, Synthetic Met., 102(1-3), 989, (1999).

- L. Sicot, C. Fiorini, A. Lorin, et al., DYE SENSITIZED POLYTHIOPHENE SOLAR CELLS, Synthetic Met, 102(1-3), 991 (1999).

- C. Fiorini, N. Prudhomme, AC Etilé, et al., ALL-OPTICAL MANIPULATION OF AZO-DYE MOLECULES, Macromol Symp., 137, 105 (1999).

- C. Fiorini, JM Nunzi, F. Charra et al., PHOTOINDUCED NONLINEAR OCTUPOLAR POLARIZATION : TRANSIENT AND PERMANENT REGIMES, J Nonlinear Opt Phys, 5(4), 653 (1996).

- JM Nunzi, F. Charra, C Fiorini, OPTICAL PREPARATION OF POLYMERS FOR PHASE-MATCHED FREQUENCY DOUBLING, Mol Cryst Liq Cryst A, 255, 85, (1994).

Article de revue
- PHOTOINDUCED NONCENTROSYMMETRY IN AZO-DYE POLYMERS USING DUAL-FREQUENCY INTERFERENCES
C. Fiorini, F. Charra, A.C. Etilé, P. Raimond and J.M. Nunzi, Advanced functional Molecules and Polymers, Chapitre 4, H.S. Nalwa Ed., Gordon and Breach.

Articles de vulgarisation

- C. Fiorini, J.M.Nunzi, F.Charra et P. Raimond, ALL-OPTICAL PATTERNING OF 3-DIMENSIONAL MICRO-STRUCTURES IN AZO-POLYMERS : TOWARDS A FULL CONTROL OF THE MOLECULAR ORDER, Photonic Science News, (1997).

- C. Fiorini, J.M.Nunzi, F.Charra et P. Raimond, OPTICAL PATTERNING OF 3-DIMENSIONAL SPATIO-TENSORIAL MICRO-STRUCTURES IN POLYMERS, Optics and Photonic news : Optics in 1996, vol. 7, 12, 12, (1996).

- J.M.Nunzi, F.Charra and C.Fiorini, ALL-OPTICAL ORIENTATION OF ORGANIC MOLECULES, Condensed Matter News, vol.2, No 4, (1993).

Brevets

- C. Allain, MP Teulade Fichou, C. Fiorini-Debuisschert, F Charra, « Nouveaux dérivés de la triphenylamine utiles comme fluorophores en biologie notamment pour la microscopie biphotonique», brevet FR06 54837 (2006).

- G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, “Procédé de traitement d’un fluide  à l’aide d’un réseau auto-organisé adsorbé sur une surface”, Brevet FR0602760 ( 2006).

- C. Fiorini-Debuisschert, V Simic, O. Vigneau, P Lebarny, « Capteur chimique tandem hautement sélectif et procédé de détection utilisant ce capteur », brevet 04-01395 (2004).

- C. Hubert, C. Fiorini-Debuisschert, JM Nunzi, P Raimond, « Procédé de fabrication de structures périodiques bi-dimensionnelles auto-organisées, en milieu polymère » , brevet WO2005105662 (2005).

- C. Sentein, C. Fiorini, A. Lorin et J.M. Nunzi « Dispositif semiconducteur en polymère comportant au moins une fonction redresseuse et procédé de fabrication d’un tel dispositif », brevet 97 01485 (1997).

- C.Fiorini, F.Charra, J.M.Nunzi, P. Raimond et A. Lorin "Procédé de fabrication de structures en polymères organiques, transparentes, auto-organisées pour la conversion de fréquence optique", brevet  9503616 (1995).

Enseignement

 1999-2004 :  Option du DEA Laser et Matière, conjoint Paris VI et XI (resp. Ch Flytzanis)
“Matériaux organiques pour l’optique non-linéaire”.

 

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