PUBLICATIONS

L. Dubois and H. Desvaux
"Accroissement de la polarisation des spins nucléaires d'une moléle via un transfert de polarisation de type Hartmann-Hahn utilisant le champ dipolaire moyen créé par une source."
Patent, FR 2881226A1, January 27^th 2005. WO 2006/079702

D. J.Y. Marion and H. Desvaux
"Procédé de réglage d'un circuit d'excitation et de détection pour résonance magnétique nucléaire et circuit d'excitation et de détection adapté à la mise en oeuvre d'un tel procédé."
Patent, FRA 0708464, EP 2 068 164, December 4, 2007.

2016-

89) M. T. Pöschko, V.V. Rodin, J. Schlagnitweit, N. Müller and H. Desvaux,^*
"Non-linear detection of secondary isotopic chemical shifts in NMR through spin noise."
Nature Communications, 8, (2017) 13914 (1-8).

2011-2015

88) G. Ferrand, M. Luong, G. Huber and H. Desvaux,^*
"Nuclear spin noise in NMR revisited."
Journal of Chemical Physics, 143, (2015) 094201 (1-10).

87) G. Ferrand,^* M. Luong, G. Huber and H. Desvaux,
"A more accurate tuning-matching technique for NMR probes using wobulation and variable phase shifter."
Concept in Magnetic Resonance part B, 45, (2015) 59-68.

86) M. T. Pöschko, J. Schlagnitweit, G. Huber, M. Nausner, M. Hornicakova, H. Desvaux^* and N. Müller^*
"On the tuning of high-resolution NMR probes."
ChemPhysChem, 15, (2014) 3639-3645. Highlighted in SpectroscopyNow.

85) V. Henner^*, H Desvaux^*, T. Belozerova, D.J.Y. Marion, P. Kharebov and A. Klots
"Collective effects due to dipolar fields as the origin of the extremely random behavior in hyperpolarized NMR maser: A theoretical and numerical study."
Journal of Chemical Physics, 139, (2013) 144111 (1-9).

84) S.W. Morgan, E. Baudin, G. Huber, P. Berthault, G. Tastevin, M. Goldman, P.J. Nacher^* and H. Desvaux^*
"Multiple echoes due to distant dipolar fields in NMR of hyperpolarized noble gas solutions."
European Physical Journal D, 67, (2013) 29 (1-10).

83) H. Desvaux^*
"Non-linear liquid-state NMR."
Progress in NMR Spectroscopy, 70, (2013) 50-71.

82) H. Desvaux^*
"Formalism and interactions in NMR."
EPJ Web of conferences, 30, (2012) 01002.

81) J. Schlagnitweit, S. W. Morgan, M. Nausner, N. Müller^* and H. Desvaux^*
"Non-linear signal detection improvement by radiation-damping in single-pulse NMR spectra."
ChemPhysChem, 13, (2012) 482-487.

80) C. Boutin, A. Stopin, T. Brotin, J.-P. Dutasta,N. Jamin, A. Sanson, Y. Boulard, F. Leteurtre, G. Huber, A. Bogaert-Buchmann, N. Tassali, H. Desvaux, M. Carrière and P. Berthault^*
"Cell Uptake of a Biosensor Detected by Hyperpolarized ¹²⁹Xe NMR: the Transferrin Case."
Bioorganic and Medicinal Chemistry, 19, (2011) 4135-4143.

79) C. Boutin, H. Desvaux, M. Carrière, F. Leteurtre, N. Jamin, Y. Boulard and P. Berthault^*
"Hyperpolarized ¹²⁹Xe NMR signature of living biological cells"
NMR in Biomedicine, 24, (2011) 1264-1269.

2006-2010

78) O. Delalande, H. Desvaux, E. Godat, A. Valleix, C. Junot, J. Labarre and Y. Boulard^*
"Cadmium-glutathione solution structures provide new keys for understanding the detoxification process."
FEBS Journal, 277, (2010) 5086-5096.

77) P. Berthault^*, H. Desvaux, T. Wendlinger, M. Gyejacquot,A. Stopin, T. Brotin, J.-P. Dutasta and Yves Boulard
"Effect of pH and counterions on the encapsulation properties of Xenon in water-soluble cryptophanes."
Chemistry, a European Journal, 16, (2010), 12941-12946.

76) H. Desvaux^*, D. J.Y. Marion, G. Huber and P. Berthault
"Nuclear spin-noise spectra of hyperpolarized systems."
Angewandte Chemie International Edition, 48, (2009) 4341-4343.

75) P. Berthault^*, G. Huber and H. Desvaux
"Biosensing using laser-polarized xenon NMR/MRI."
Progress in NMR Spectroscopy, 55, (2009) 35-60.

74) S. Prévost, H. Coulombeau, K. Baczko, L. Berthon, N. Zorz, H. Desvaux, F. Testard, T. Zemb and C. Larpent^*
"Thermo-responsive metal-chelating surfactants: properties and use in cloud point extraction of uranyl nitrate."
Tendside Surfactants Detergents (2009) 100-104.

73) D. J. Y. Marion, P. Berthault and H. Desvaux^*
"Spectral and temporal features of multiple spontaneous NMR-maser emissions."
European Physical Journal D, 51, (2009) 357-367.

72) F. Lerouge, O. Melnyk, J.-O. Durand^*, L. Raehm, P. Berthault^*, G. Huber, H. Desvaux, A. Constantinesco, P. Choquet, J. Detour and M. Smaïhi
"Towards thrombosis-targeted Zeolite nanoparticles for laser-polarized ¹²⁹Xe MRI."
Journal of Material Chemistry, 19, (2009) 379-386.

71) P. Berthault^*, A. Bogaert-Buchmann, H. Desvaux, G. Huber and Y. Boulard
"Sensitivity and multiplexing capabilities of MRI based on polarized ¹²⁹Xe biosensors."
Journal of the American Chemical Society, 130,(2008) 16456-16457.

70) G. Huber, L. Beguin, H. Desvaux, T. Brotin, H. A. Fogarty, J.-P. Dutasta and P. Berthault^*
"Cryptophane-Xenon complexes in organic solvents observed through NMR spectroscopy."
Journal of Physical Chemistry A, 112, (2008) 11362-11372.

69) D. J. Marion, G. Huber, P. Berthault and H. Desvaux^*
"Observation of noise-triggered chaotic emissions in an NMR-maser."
ChemPhysChem, 10, (2008) 1395-1401.

68) D. J. Marion, G. Huber, P. Berthault and H. Desvaux^*
"Cover picture: Chaotic emissions in an NMR-maser."
ChemPhysChem, 10, (2008) 1349.

67) D. J. Marion, and H. Desvaux^*
"An alternative tuning approach to enhance NMR signals."
Journal of magnetic Resonance, 193, (2008) 153-157.

66) D. J. Marion, G. Huber, L. Dubois, P. Berthault and H. Desvaux^*
"Effects on ¹H and ¹²⁹Xe NMR spectra of large magnetization created by dissolved laser-polarized xenon."
Comptes-Rendus Chimie, 11, (2008) 553-559.

65) H. A. Fogarty, P. Berthault, T. Brotin^*, G. Huber, H. Desvaux and J.-P. Dutasta^*
"A cryptophane core optimized for xenon encapsulation."
Journal of the American Chemical Society, 129, (2007) 10332-10333.

64) V. Roy, T. Brotin, J.-P. Dutasta, M.-H. Charles, T. Delair, F. Mallet, G. Huber, H. Desvaux, Y. Boulard and P. Berthault^*
"A cryptophane biosensor for detection of specific nucleotide targets through xenon-NMR."
ChemPhysChem, 8, (2007) 2082-2085.

63) D. J. Marion, G. Huber, L. Dubois, P. Berthault and H. Desvaux^*
"¹H and ¹²⁹Xe NMR absorption line shapes in the presence of highly polarized and concentrated xenon solutions in high magnetic field."
Journal of Magnetic Resonance, 187, (2007) 78-87.

62) H. Desvaux^*, D. J. Marion, G. Huber, L. Dubois and P. Berthault
"Direct enhancement of any solution NMR signal using the distant dipolar fields created by highly polarized and highly concentrated nuclear spin systems."
European Physical Journal, Applied-Physics, 36, (2006) 25-34.

61) F. Alvarez-Salgado, H. Desvaux and Y. Boulard^*
"NMR solution structures of a DNA dodecamer containing a tandem G-T mismatch using NOE and residual dipolar couplings."
Magnetic Resonance in Chemistry, 44, (2006) 1081-1089.

60) G. Huber, T. Brotin, L. Dubois, H. Desvaux, J.-P. Dutasta and P. Berthault^*
"Water soluble cryptophanes showing unprecendeted affinity for xenon: candidates as NMR-based biosensors."
Journal of the American Chemical Society, 128, (2006) 6239-6246.

59) P. Berthault^*, G. Huber, P.-T. Ha, L. Dubois, H. Desvaux and E. Guittet
"Study of the hydrophobic cavity of $beta$-cryptogein through laser-polarized xenon NMR spectroscopy."
ChemBioChem, 7, (2006) 59-64.

2001-2005

58) H. Desvaux^*, L. Dubois, G. Huber, M.L. Quillin, P. Berthault and B.W. Matthews
"Dynamics of xenon binding inside the hydrophobic cavity of pseudo wild-type bacteriophage T4 lysozyme explored through xenon-based NMR."
Journal of the American Chemical Society, 127, (2005) 11676-11683.

57) P. Berthault and H. Desvaux^*
"Dissolution of laser-polarized xenon in benzene."
Magnetic Resonance Imaging, 23, (2005) 315-316.

56) L. Dubois, P. Da Silva, C. Landon, J.G. Huber, M. Ponchet, F. Vovelle, P. Berthault and H. Desvaux^*
"Probing the hydrophobic cavity of Lipid Transfer Protein from Nicotiana tabacum through Xenon-based NMR."
Journal of the American Chemical Society, 126, (2004) 15738-15746.

55) J.G. Huber, L. Dubois, H. Desvaux, J.P. Dutasta, T. Brotin and P. Berthault^*
"NMR study of optically active monosubstituted cryptophanes and their interaction with xenon."
Journal of Physical Chemistry A, 108, (2004) 9608-9615.

54) L. Dubois, P. Berthault^*, J.G. Huber and H. Desvaux^*
"Mapping hydrophobic molecular regions using dissolved laser-polarized xenon NMR."
Comptes Rendus Physique, 5, (2004) 305-313.

53) H. Desvaux^*
"Highly polarized nuclear spin systems and dipolar interactions in NMR - Foreword."
Comptes Rendus Physique,5, (2004) 293-295.

52) H. Desvaux^*, R. Kümmerle, J. Kowalewski, C. Luchinat and I. Bertini
"Direct measurement of dynamic frequency shift associated to cross-correlation in ¹⁵N enriched proteins."
ChemPhysChem, 5, (2004) 959-965.

51) L. Dubois, S. Parrès, J.G. Huber, P. Berthault and H. Desvaux^*
"Dynamics of xenon inside hydrophobic cavities as probed by NMR relaxation of dissolved laser-polarized xenon."
Journal of Physical Chemistry B, 108, (2004) 767-773; ibid 15952.

50) F. Alvarez Salgado^*, P.Berthault, Y. Boulard and H. Desvaux
"Comparison of the solution structures of a DNA dodecamer using nOe and residual dipolar coupling data."
Comptes Rendus Chimie, 7, (2004) 259-263.

49) A. Davidson^*, P. Berthault and H. Desvaux
"Silicas of unimodal and bimodal porosities probed by ¹²⁹Xe NMR spectroscopy."
Journal of Physical Chemistry B, 107, (2003) 14388-14393.

48) H. Desvaux, J.G. Huber, T. Brotin, J.P. Dutasta and P. Berthault^*
"Magnetization transfer from laser-polarized xenon to protons with spin-diffusion quenching."
ChemPhysChem, 4, (2003) 383-387.

47) P. Berthault, D. Jeannerat, F. Camerel, F. Alvarez-Salgado, Y. Boulard, J.-C. P. Gabriel and H. Desvaux^*
"Dilute liquid crystals used to enhance residual dipolar couplings may alter conformational equilibrium in oligosaccharides."
Carbohydrate Research, 338, (2003) 1771-1785.

46) P. Berthault and H. Desvaux^*
"NMR study of the dissolution of laser-polarized xenon."
European Physical Journal D, 22, (2003) 65-73.

45) J.-C. P. Gabriel^*, F. Camerel, B. J. Lemaire, H. Desvaux, P. Davidson and P. Batail
"Swollen liquid-crystalline lamellar phase based on extended colloidal solid-like sheets. Application for the structure determination of biomolecules using NMR."
Abstract of papers of the American Chemical Society, 223, (2002) 144-Coll.

44) J.-C. P. Gabriel^*, F. Camerel, B. J. Lemaire, H. Desvaux, P. Davidson^* and P. Batail
"Swollen liquid-crystalline lamellar phase based on extended solid-like sheets."
Nature, 413, (2001) 504-508.

43) C. Landon, P. Berthault, F. Vovelle and H. Desvaux^*
"Magnetization transfer from laser-polarized xenon to protons located in the hydrophobic cavity of the wheat non-specific lipid transfer protein"
Protein Science, 10, (2001) 762-770.

42) P.Berthault, C. Landon, F. Vovelle and H. Desvaux^*
"Première détection d'un transfert d'aimantation entre du xénon polarisé par laser et des protons d'une protéine"
Comptes Rendus de l'Académie des Sciences, Série IV, 2 (2001) 327-332.

41) H. Desvaux^*, J.C. P. Gabriel^*, P. Berthault and F. Camerel
"First use of a mineral liquid crystal for NMR measurement of residual dipolar couplings of a non-labeled >biomolecule."
Angewandte Chemie International Edition, 40, (2001) 373-376.

1996-2000

40) H. Desvaux, T. Gautier, G. Le Goff, M. Pétro and P. Berthault^*
"Direct evidence of a magnetization transfer between laser-polarized xenon and protons of a cage-molecule in water."
European Physical Journal D, 12, (2000) 289-296.

39) Y.-M. Zhang, B. Dausse, P. Sinaÿ^*, M. Afsahi, P. Berthault and H. Desvaux
"Synthesis and NMR study of a heptasaccharide, epitope of the stage specific antigen-1 (SSEA-1)."
Carbohydrate Research, 324, (2000) 231-234.

38) M. Guenneugues, P. Berthault, H. Desvaux^* and M. Goldman
"Direct determination of the heteronuclear T₁/T₂ ratio by off-resonance steady-state magnetization measurement: Investigation of the possible application to fast exchange characterization of ¹⁵N-labeled proteins."
Journal of Biomolecular NMR, 15, (1999) 295-307.

37) P. Berthault, H. Desvaux^*, G. Le Goff and M. Pétro
"A simple way to properly invert intense nuclear magnetization: application to laser-polarized xenon."
Chemical Physics Letters, 314, (1999) 52-56.

36) Th. E. Malliavin^*, H. Desvaux and M.-A. Delsuc
"Quantitative determination of longitudinal and transverse cross-relaxation rates."
Journal de Chimie-Physique, 96, (1999) 1608-1615.

35) Th. E. Malliavin^*, H. Desvaux, A. Aumelas, A. Chavanieu and M.-A. Delsuc
"The structuring of ranalexin observed by quantitative measurement of longitudinal and transverse cross-relaxation rates."
Journal of Magnetic Resonance, 140, (1999) 189-199.

34) B. Henry, H. Desvaux, M. Prischepa, P. Berthault^*, Y.-M. Zhang, J.-M. Mallet, J. Esnault and P. Sinaÿ
"NMR study of a Lewis^X pentasaccharide derivative: solution structure and interaction with cations."
Carbohydrate Research, 315, (1999) 48-62.

33) H. Desvaux^* and P. Berthault
"Study of dynamic processes in liquids using off-resonance rf irradiation."
Progress in NMR Spectroscopy, 35, (1999) 295-340.

32) H. Desvaux^* and M. Gochin
"Coherence transfer between nuclear spins in paramagnetic systems: Effects of nucleus-electron dipole-dipole cross correlation."
Molecular Physics, 96, (1999) 1317-1333.

31) M. Guenneugues, P. Berthault and H. Desvaux^*
"A method for determining B₁ field inhomogeneity. Are the biases assumed in heteronuclear relaxation experiments usually underestimated?"
Journal of Magnetic Resonance, 136, (1999) 118-126.

30) I.C. Felli, H. Desvaux and G. Bodenhausen^*
"Using cross-correlation rates to characterize the dynamics of ¹⁵N labeled proteins. Application to paramagnetic protein."
Journal of Biomolecular NMR, 12, (1998) 509-521.

29) Th. E. Malliavin^*, H. Desvaux, and M.-A. Delsuc
"Conditions for the measurement of quantitative off-resonance ROESY intensities."
Magnetic Resonance in Chemistry, 36, (1998) 801-806.

28) C. Wary^*, H. Desvaux, M. Van Cauteren, F. Vanstapel, P. Carlier and P. Jehenson
"¹H NMR study of the dynamic properties of glycogen in solution by steady-state magnetization measurement in presence of off-resonance irradiation."
Carbohydrate Research, 306, (1998) 479-491.

27) S. Zinn-Justin^*, P. Berthault, M. Guenneugues and H. Desvaux
"Off-resonannce rf fields in heteronuclear NMR. Application to the study of slow motions."
Journal of Biomolecular NMR, 10, (1997), 363-372.

26) H. Desvaux^*
"Measurement of homonuclear cross-correlation rates along an effective field: Application to dipole-dipole cross-correlation."
Journal of Magnetic Resonance, 127, (1997) 1-16.

25) D. Jeannerat, A. Blue, B. Boulat, B. Cutting, H. Desvaux, I. Felli, R. Fu, J. Huth T. Meersmann, N. Murali, P. Mutzenhardt, J.A. Palmer, P. Pelupessy, C. Peng, M. Schwager, S. Smith, S.J.F. Vincent, C. Zwahlen and G. Bodenhausen^*
"Two years of NMR developments at the National High Magnetic Field Laboratory in Tallahassee, USA."
Chimia, 50, (1996), 633-638.

24) M. Goldman^* and H. Desvaux
"Cross-precession induced by the average dipolar field in high-resolution NMR."
Chemical Physics Letters, 256, (1996), 497-501.

23) G. Lippens^*, J.-M. Wieruszeski, P. Talaga, J.-P. Bohin and H. Desvaux
"Correlation between the anomeric proton chemical shifts and precise interglycosidic distances measurements in the cyclic glucan of Burkholderia solanacearum."
Journal of the American Chemical Society, 118, (1996), 7227-7228.

22) P. Berthault^*, N. Birlirakis, G. Rubinstenn, P. Sinaÿ and H. Desvaux
"Solution structure of a Lewis^X analogue by off-resonance ¹H NMR spectroscopy without use of internal distance reference."
Journal of Biomolecular NMR, 8, (1996), 23-35.

21) H. Desvaux^* and P. Berthault
"Apports des champs rf hors résonance aux études structurales et dynamiques en RMN liquide."
Journal de Chimie-Physique, 93, (1996), 403-426.

20) N. Birlirakis^*, P. Berthault, H. Desvaux, M. Goldman, T.E. Malliavin, M. Piotto
"Off-resonance ROESY: a new ¹H-NMR method for the simultaneous study of molecular structure and dynamics."
Bruker Reports, 142, (1996), 34-38.

19) H. Desvaux^* and M. Goldman
"A simple solution to decrease angular dispersion in off-resonance experiments."
Journal of Magnetic Resonance Series B, 110, (1996) 198-201.

1991-1995

18) H. Desvaux^*, N. Birlirakis, Cl. Wary and P. Berthault
"Study of slow molecular motions in solution using off-resonance irradiation in homonuclear NMR. Part II: Fast chemical exchange processes."
Molecular Physics, 86, (1995) 1059-1073.

17) H. Desvaux^*, Cl. Wary, N. Birlirakis and P. Berthault
"Study of slow molecular motions in solution using off-resonance irradiation in homonuclear NMR. Part I: Long dipolar correlation times."
Molecular Physics, 86, (1995) 1048-1058.

16) P. Berthault^*, D. Duchesne, H. Desvaux and B. Gilquin
"A self inclusion complex with beta-cyclodextrin studied by NMR and molecular modeling."
Carbohydrate Research, 276, (1995) 267-287.

15) H. Desvaux^*, P. Berthault, N. Birlirakis, M. Goldman and M. Piotto
"Improved versions of off-resonance ROESY."
Journal of Magnetic Resonance, Series A, 113, (1995) 47-52.

14) H. Desvaux^*, P. Berthault and N. Birlirakis
"Dipolar spectral densities from off-resonance ¹H-NMR relaxation measurements."
Chemical Physics Letters, 233, (1995) 545-549.

13) H. Desvaux^*, P. Berthault, N. Birlirakis and M. Goldman
"Off-resonance ROESY: for the study of dynamics processes."
Journal of Magnetic Resonance, Series A, 108, (1994) 219-229.

12) H. Desvaux^* and M. Goldman
"A new NMR method for measuring the local correlation times of molecules in liquid state."
Journal de Chimie-Physique, 91, (1994) 653-659.

11) H. Desvaux^*, P. Berthault, N. Birlirakis and M. Goldman
"A new NMR method for studying the dynamics of the molecule: Off-resonance ROESY."
Journal de Chimie-Physique, 91, (1994) 646-652.

10) Ph. Lux, F. Brunet^*, H. Desvaux and J. Virlet
"Two dimensional ²⁹Si-²⁹Si INEPT DQF COSY NMR for the structure of alkoxysilanes Polymers in solutions."
Journal de Chimie-Physique, 91, (1994) 409-418.

9) H. Desvaux and M. Goldman^*
"A new NMR method for measuring the rotational correlation time of molecules in the liquid state."
Molecular Physics, 81, (1994) 955-975.

8) M. Goldman^* and H. Desvaux
"Nouvelle méthode d'investigation de la dynamique locale des molécules en phase liquide par R.M.N.."
Compte-Rendu de l'Académie des Sciences, Paris, 317 Série II, (1993) 749-756.

7) H. Desvaux^*, P. Berthault, N. Birlirakis and M. Goldman
"ROESY hors résonance: Une nouvelle méthode d'étude de la relaxation par R.M.N.."
Compte-Rendu de l'Académie des Sciences, Paris, 317 Série II, (1993) 19-25.

6) Ph. Lux, F. Brunet^*, H. Desvaux and J. Virlet
"Determination of the structure of alkoxysilanes polymers in solutions by ²⁹Si-²⁹Si INEPT DQF COSY NMR."
Magnetic Resonance in Chemistry, 31, (1993) 623-631.

5) P. Berthault^*, H. Desvaux and B. Perly
"Simple solutions to resolve extreme spectral overcrowding in soft 2D NMR experiments."
Magnetic Resonance in Chemistry, 31, (1993) 259-265.

4) H. Desvaux^*
"Comment on: Magnetic field-dependent nuclear spin-spin coupling constant."
Magnetic Resonance in Chemistry, 30, (1992) 1031.

3) H. Desvaux^*
"Nouvelles expressions de l'Hamiltonien< de constante de couplage indirect entre spins nucléaires. - Application à la variation avec le champ magnétique externe-."
Journal de Chimie-Physique, 89, (1992) 1-23.

2) P. Battioni, O. Brigaud, H. Desvaux, D. Mansuy^* and T. G. Traylor
"Preparation of functionalized polyhalogenated tetraaryl porphyrins by selective substitution of p-fluorines of meso-tetra (pentafluorophenyl) porphyrins."
Tetrahedron Letters, 32, (1991) 2893-2896.

1) P.Berthault^* and H. Desvaux
"R.M.N. par détection inverse."
Rapport CEA-R-5547, (1991) 1-72.